Poly[[(μ2-benzene-1,4-dicarboxyl­ato-κ4 O 1,O 1′:O 4,O 4′)(μ2-di-4-pyridyldiazene-κ2 N 1:N 1′)cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]

نویسندگان

  • Chao-Xia Chu
  • Ying Zhang
  • Hu Zhou
  • Ai-Hua Yuan
چکیده

In the title compound, {[Co(C(8)H(4)O(4))(C(10)H(8)N(4))]·2C(3)H(7)NO·0.5H(2)O}(n), the Co(II) atom is six-coordinated by four O atoms from two benzene-1,4-dicarboxyl-ate (H(2)bdc(2-)) groups and two N atoms from two 4,4'-azopyridine (4,4'-azpy, or di-4-pyridyldiazene) ligands, leading to a distorted octa-hedral geometry. The structure consists of two-dimensional corrugated sheets with a 4(4) topology in an …ABAB… packing pattern stacking along the a axis. The separation of the adjacent corrugated sheets is ca. 8.561 (2)  Å (Co⋯Co distance) along the a axis. The uncoordinated water molecule is half-occupied. The crystal structure is stabilized by O-H⋯N and C-H⋯O hydrogen-bonding inter-actions.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009